19-03-2011, 04:19 PM
PRESENTED BY-
PRASHANT KAUSHAL
[attachment=10595]
BATTERIES THAT CHARGES ON AIR
INTRODUCTION
Lithium-ion batteries power most of the mobile devices like:
Laptops
Cell phones
Portable Playstation.
Merits of li-ion
lithium is the lightest of all metals, has the greatest electrochemical potential and provides the largest energy density for weight.
Because of the inherent instability of lithium metal, especially during charging, research shifted to a non-metallic lithium battery using lithium ions.
The energy density of lithium-ion is typically twice that of the standard nickel-cadmium.
Lithium-ion is a low maintenance battery, The high cell voltage of 3.6 volts allows battery pack designs with only one cell.
lithium-ion cells cause little harm when disposed.
Demerits of Li-ion
It is fragile and requires a protection circuit to maintain safe operation.
Subject to aging, even if not in use - storage in a cool place at 40% charge reduces the aging effect.
Lithium ion batteries are energy limited.
Li-air batteries
Arthur Dobley, metal air battery scientist, explains “Li-air batteries breathe oxygen from the air, and allow it to react with the Li metal anode. These are constructed in layers, like a sandwich, of the lithium metal anode, separator with electrolyte and then the air cathode . the air cathode is the critical part, and that is where oxygen enters to cells and reacts.”
PROF. Peter J. Hall explains:
“The capacity of Li-air batteries is 10-20 times greater than traditional Li-ion batteries. These will also be considerably cheaper as they contain very little heavy metal content”.
These are environment friendly.
Lithium content in them can be recycled.
Li-air battery is very lighter than Li-ion battery.
construction
The anode, separator, electrolyte and carbon air cathodes are sealed inside the metallised plastic packets.
For experimental purpose, a pouch cell is used, which contains an air cathode inside the Li-air cells.
ANODE:
Anode is composed of a lithium metal foil.
Its is pressed into a nickel mesh current collector.
The area of anode is slightly larger than the cathode by 10 cm-sq.
SEPARATOR & ELECTROLYTE:
Setela, an organic polymer, is used as the separator and the liquid electrolyte used is ethyl carbonate, diethyl carbonate and dimethyl carbonate.
CATHODE:
cathode composite carbon, a metal catalyst and a binder deposited on metal collector.
The binder is Teflon combined with latex and the metal current collector is nickel.
On both sides of metal current collector, two layers of carbon, binder and catalyst mixtures are deposited.
A thin Teflon film between the air cathode and the atmosphere repels atmospheric water but allows oxygen diffusion.
THE FUTURE
So far so good but what is future of Li-ion batteries.
The future of Li-air is continued development of components such as anode, electrolyte, separator and air cathode.
Efforts to increase the number of cycles available as well as reduce packaging size are on the road map to a viable Li-air system.
On a brief note
Characteristics
Capacity
Weight
Cost
Lithium-air battery
Ten times more capacity than Li-ion batteries.
Lighter than Li-ion and other cells, as the cathode is oxygen.
Less, because of use of Li and cathode of its oxygen which is absorbed from air.
PRASHANT KAUSHAL
[attachment=10595]
BATTERIES THAT CHARGES ON AIR
INTRODUCTION
Lithium-ion batteries power most of the mobile devices like:
Laptops
Cell phones
Portable Playstation.
Merits of li-ion
lithium is the lightest of all metals, has the greatest electrochemical potential and provides the largest energy density for weight.
Because of the inherent instability of lithium metal, especially during charging, research shifted to a non-metallic lithium battery using lithium ions.
The energy density of lithium-ion is typically twice that of the standard nickel-cadmium.
Lithium-ion is a low maintenance battery, The high cell voltage of 3.6 volts allows battery pack designs with only one cell.
lithium-ion cells cause little harm when disposed.
Demerits of Li-ion
It is fragile and requires a protection circuit to maintain safe operation.
Subject to aging, even if not in use - storage in a cool place at 40% charge reduces the aging effect.
Lithium ion batteries are energy limited.
Li-air batteries
Arthur Dobley, metal air battery scientist, explains “Li-air batteries breathe oxygen from the air, and allow it to react with the Li metal anode. These are constructed in layers, like a sandwich, of the lithium metal anode, separator with electrolyte and then the air cathode . the air cathode is the critical part, and that is where oxygen enters to cells and reacts.”
PROF. Peter J. Hall explains:
“The capacity of Li-air batteries is 10-20 times greater than traditional Li-ion batteries. These will also be considerably cheaper as they contain very little heavy metal content”.
These are environment friendly.
Lithium content in them can be recycled.
Li-air battery is very lighter than Li-ion battery.
construction
The anode, separator, electrolyte and carbon air cathodes are sealed inside the metallised plastic packets.
For experimental purpose, a pouch cell is used, which contains an air cathode inside the Li-air cells.
ANODE:
Anode is composed of a lithium metal foil.
Its is pressed into a nickel mesh current collector.
The area of anode is slightly larger than the cathode by 10 cm-sq.
SEPARATOR & ELECTROLYTE:
Setela, an organic polymer, is used as the separator and the liquid electrolyte used is ethyl carbonate, diethyl carbonate and dimethyl carbonate.
CATHODE:
cathode composite carbon, a metal catalyst and a binder deposited on metal collector.
The binder is Teflon combined with latex and the metal current collector is nickel.
On both sides of metal current collector, two layers of carbon, binder and catalyst mixtures are deposited.
A thin Teflon film between the air cathode and the atmosphere repels atmospheric water but allows oxygen diffusion.
THE FUTURE
So far so good but what is future of Li-ion batteries.
The future of Li-air is continued development of components such as anode, electrolyte, separator and air cathode.
Efforts to increase the number of cycles available as well as reduce packaging size are on the road map to a viable Li-air system.
On a brief note
Characteristics
Capacity
Weight
Cost
Lithium-air battery
Ten times more capacity than Li-ion batteries.
Lighter than Li-ion and other cells, as the cathode is oxygen.
Less, because of use of Li and cathode of its oxygen which is absorbed from air.