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Analog Electronics Tutorial Series DIODES


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What Are Diodes Made Out Of?

Silicon (Si) and Germanium (Ge) are the two most common single elements that are used to make Diodes. A compound that is commonly used is Gallium Arsenide (GaAs), especially in the case of LEDs because of it’s large bandgap.
Silicon and Germanium are both group 4 elements, meaning they have 4 valence electrons. Their structure allows them to grow in a shape called the diamond lattice.
Gallium is a group 3 element while Arsenide is a group 5 element. When put together as a compound, GaAs creates a zincblend lattice structure.
In both the diamond lattice and zincblend lattice, each atom shares its valence electrons with its four closest neighbors. This sharing of electrons is what ultimately allows diodes to be build. When dopants from groups 3 or 5 (in most cases) are added to Si, Ge or GaAs it changes the properties of the material so we are able to make the P- and N-type materials that become the diode.


P-Type Material


P-type material is produced when the dopant that is introduced is from Group III. Group III elements have only 3 valence electrons and therefore there is an electron missing. This creates a hole (h+), or a positive charge that can move around in the material. Commonly used Group III dopants are aluminum, boron, and gallium.
The 2D diagram to the left shows the hole that will be present when a Group III dopant is introduced to a material such as silicon. This hole is quite mobile in the same way the extra electron is mobile in a n-type material

The Biased PN Junction


In forward bias the depletion region shrinks slightly in width. With this shrinking the energy required for charge carriers to cross the depletion region decreases exponentially. Therefore, as the applied voltage increases, current starts to flow across the junction. The barrier potential of the diode is the voltage at which appreciable current starts to flow through the diode. The barrier potential varies for different materials.