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Gas Sensor


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Construction

The sensors contain two in contact with an electrolyte. The electrodes are typically fabricated by fixing a high surface area precious metal on to the porous hydrophobic membrane. The working electrode contacts both the electrolyte and the ambient air to be monitored usually via a porous membrane. The electrolyte most commonly used is a mineral acid The electrodes and housing are usually in a plastic housing which contains a gas entry hole for the gas and electrical contacts.

Theory of operation

The gas diffuses into the sensor, through the back of the porous membrane to the working electrode where it is oxidized or reduced. This electrochemical reaction results in an electric current that passes through the external circuit. In addition to measuring, amplifying and performing other signal processing functions, the external circuit maintains the voltage across the sensor between the working and counter electrodes for a two electrode sensor or between the working and reference electrodes for a three electrode cell. At the counter electrode an equal and opposite reaction occurs, such that if the working electrode is an oxidation, then the counter electrode is a reduction.