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Electron


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Introduction

An electron has no known components or substructure; in other words, it is generally thought to be an elementary particle.[2] An electron has a mass that is approximately 1/1836 that of the proton.[9] The intrinsic angular momentum (spin) of the electron is a half-integer value in units of ħ, which means that it is a fermion. The antiparticle of the electron is called the positron; it is identical to the electron except that it carries electrical and other charges of the opposite sign. When an electron collides with a positron, both particles may be totally annihilated, producing gamma ray photons.
Electrons, which belong to the first generation of the lepton particle family,[10] participate in gravitational, electromagnetic and weak interactions.[11] Like all matter, they have quantum mechanical properties of both particles and waves, so they can collide with other particles and can be diffracted like light. However, this duality is best demonstrated in experiments with electrons, due to their tiny mass. Since an electron is a fermion, no two electrons can occupy the same quantum state, in accordance with the Pauli exclusion principle.[10]
The concept of an indivisible quantity of electric charge was theorized to explain the chemical properties of atoms, beginning in 1838 by British natural philosopher Richard Laming;[4] the name electron was introduced for this charge in 1894 by Irish physicist George Johnstone Stoney. The electron was identified as a particle in 1897 by J. J. Thomson and his team of British physicists.[6][12][13]
In many physical phenomena, such as electricity, magnetism, and thermal conductivity, electrons play an essential role. An electron in motion relative to an observer generates a magnetic field, and will be deflected by external magnetic fields. When an electron is accelerated, it can absorb or radiate energy in the form of photons. Electrons, together with atomic nuclei made of protons and neutrons, make up atoms. However, electrons contribute less than 0.06% to an atom's total mass. The attractive Coulomb force between an electron and a proton causes electrons to be bound into atoms. The exchange or sharing of the electrons between two or more atoms is the main cause of chemical bonding.[14]
According to theory, most electrons in the universe were created in the big bang, but they may also be created through beta decay of radioactive isotopes and in high-energy collisions, for instance when cosmic rays enter the atmosphere. Electrons may be destroyed through annihilation with positrons, and may be absorbed during nucleosynthesis in stars. Laboratory instruments are capable of containing and observing individual electrons as well as electron plasma, whereas dedicated telescopes can detect electron plasma in outer space. Electrons have many applications, including welding, cathode ray tubes, electron microscopes, radiation therapy, lasers and particle accelerators.

History

The ancient Greeks noticed that amber attracted small objects when rubbed with fur. Apart from lightning, this phenomenon is humanity's earliest recorded experience with electricity.[15] In his 1600 treatise De Magnete, the English scientist William Gilbert coined the New Latin term electricus, to refer to this property of attracting small objects after being rubbed.[16] Both electric and electricity are derived from the Latin ēlectrum (also the root of the alloy of the same name), which came from the Greek word for amber, ήλεκτρον (ēlektron).
In 1737, C. F. du Fay and Hawksbee independently discovered what they believed to be two kinds of frictional electricity; one generated from rubbing glass, the other from rubbing resin. From this, Du Fay theorized that electricity consists of two electrical fluids, "vitreous" and "resinous", that are separated by friction and that neutralize each other when combined.[17] A decade later Benjamin Franklin proposed that electricity was not from different types of electrical fluid, but the same electrical fluid under different pressures. He gave them the modern charge nomenclature of positive and negative respectively.[18] Franklin thought that the charge carrier was positive.[19]

Atomic theory

The Bohr model of the atom, showing states of electron with energy quantized by the number n. An electron dropping to a lower orbit emits a photon equal to the energy difference between the orbits.
By 1914, experiments by physicists Ernest Rutherford, Henry Moseley, James Franck and Gustav Hertz had largely established the structure of an atom as a dense nucleus of positive charge surrounded by lower-mass electrons.[39] In 1913, Danish physicist Niels Bohr postulated that electrons resided in quantized energy states, with the energy determined by the angular momentum of the electron's orbits about the nucleus. The electrons could move between these states, or orbits, by the emission or absorption of photons at specific frequencies. By means of these quantized orbits, he accurately explained the spectral lines of the hydrogen atom.[40] However, Bohr's model failed to account for the relative intensities of the spectral lines and it was unsuccessful in explaining the spectra of more complex atoms.[39]
Chemical bonds between atoms were explained by Gilbert Newton Lewis, who in 1916 proposed that a covalent bond between two atoms is maintained by a pair of electrons shared between them.[41] Later, in 1923, Walter Heitler and Fritz London gave the full explanation of the electron-pair formation and chemical bonding in terms of quantum mechanics.[42] In 1919, the American chemist Irving Langmuir elaborated on the Lewis' static model of the atom and suggested that all electrons were distributed in successive "concentric (nearly) spherical shells, all of equal thickness".[43] The shells were, in turn, divided by him in a number of cells each containing one pair of electrons. With this model Langmuir was able to qualitatively explain the chemical properties of all elements in the periodic table,[42] which were known to largely repeat themselves according to the periodic law.[44]