04-07-2012, 02:36 PM
plasma
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In physics and chemistry, plasma is a state of matter similar to gas in which a certain portion of the particles are ionized. Heating a gas may ionize its molecules or atoms (reduce or increase the number of electrons in them), thus turning it into a plasma, which contains charged particles: positive ions and negative electrons or ions. Ionization can be induced by other means, such as strong electromagnetic field applied with a laser or microwave generator, and is accompanied by the dissociation of molecular bonds, if present.
The presence of a non-negligible number of charge carriers makes the plasma electrically conductive so that it responds strongly to electromagnetic fields. Plasma, therefore, has properties quite unlike those of solids, liquids, or gases and is considered a distinct state of matter. Like gas, plasma does not have a definite shape or a definite volume unless enclosed in a container; unlike gas, under the influence of a magnetic field, it may form structures such as filaments, beams and double layer. Some common plasmas are found in stars and neon signs. In the universe, plasma is the most common state of matter for ordinary matter, most of which is in the rarefied intergalactic plasma (particularly intracluster medium) and in stars.
Plasmas are by far the most common phase of matter in the universe, both by mass and by volume. All the stars are made of plasma, and even the space between the stars is filled with a plasma, albeit a very sparse one. In our solar system, the planet Jupiter accounts for most of the non-plasma, only about 0.1% of the mass and 10−15% of the volume within the orbit of Pluto. Very small grains within a gaseous plasma will also pick up a net negative charge, so that they in turn may act like a very heavy negative ion component of the plasma
Definition of a plasma
Plasma is loosely described as an electrically neutral medium of positive and negative particles (i.e. the overall charge of a plasma is roughly zero). It is important to note that although they are unbound, these particles are not ‘free’. When the charges move they generate electrical currents with magnetic fields, and as a result, they are affected by each other’s fields. This governs their collective behavior with many degrees of freedom. A definition can have three criteria:
1. The plasma approximation: Charged particles must be close enough together that each particle influences many nearby charged particles, rather than just interacting with the closest particle (these collective effects are a distinguishing feature of a plasma). The plasma approximation is valid when the number of charge carriers within the sphere of influence (called the Debye sphere whose radius is the Debye screening length) of a particular particle is higher than unity to provide collective behavior of the charged particles. The average number of particles in the Debye sphere is given by the plasma parameter, "Λ" (the Greek letter Lambda).
2. Bulk interactions: The Debye screening length (defined above) is short compared to the physical size of the plasma. This criterion means that interactions in the bulk of the plasma are more important than those at its edges, where boundary effects may take place. When this criterion is satisfied, the plasma is quasineutral.
3. Plasma frequency: The electron plasma frequency (measuring plasma oscillations of the electrons) is large compared to the electron-neutral collision frequency (measuring frequency of collisions between electrons and neutral particles). When this condition is valid, electrostatic interactions dominate over the processes of ordinary gas kinetics.
Degree of ionization
For plasma to exist, ionization is necessary. The term "plasma density" by itself usually refers to the "electron density", that is, the number of free electrons per unit volume. The degree of ionization of a plasma is the proportion of atoms that have lost (or gained) electrons, and is controlled mostly by the temperature. Even a partially ionized gas in which as little as 1% of the particles are ionized can have the characteristics of a plasma (i.e., response to magnetic fields and high electrical conductivity). The degree of ionization, α is defined as α =ni/(ni + na) where ni is the number density of ions and na is the number density of neutral atoms. The electron density is related to this by the average charge state <Z> of the ions through ne = <Z> ni where ne is the number density of electrons.
Temperatures
Plasma temperature is commonly measured in kelvins or electronvolts and is, informally, a measure of the thermal kinetic energy per particle. Very high temperatures are usually needed to sustain ionization, which is a defining feature of a plasma. The degree of plasma ionization is determined by the "electron temperature" relative to the ionization energy, (and more weakly by the density), in a relationship called the Saha equation. At low temperatures, ions and electrons tend to recombine into bound states—atoms, and the plasma will eventually become a gas.
Examples of industrial/commercial plasma
Because of their sizable temperature and density ranges, plasmas find applications in many fields of research, technology and industry. For example, in: industrial and extractive metallurgy, surface treatments such as thermal spraying (coating), etching in microelectronics, metal cutting and welding; as well as in everyday vehicle exhaust cleanup and fluorescent/luminescent lamps, while even playing a part in supersonic combustion engines for aerospace engineering.
Low-pressure discharges
Glow discharge plasmas: non-thermal plasmas generated by the application of DC or low frequency RF (<100 kHz) electric field to the gap between two metal electrodes. Probably the most common plasma; this is the type of plasma generated within fluorescent light tubes.
Capacitively coupled plasma (CCP): similar to glow discharge plasmas, but generated with high frequency RF electric fields, typically 13.56 MHz. These differ from glow discharges in that the sheaths are much less intense. These are widely used in the microfabrication and integrated circuit manufacturing industries for plasma etching and plasma enhanced chemical vapor deposition.
Inductively coupled plasma (ICP): similar to a CCP and with similar applications but the electrode consists of a coil wrapped around the discharge volume that inductively excites the plasma.
Wave heated plasma: similar to CCP and ICP in that it is typically RF (or microwave), but is heated by both electrostatic and electromagnetic means. Examples are helicon discharge, electron cyclotron resonance (ECR), and ion cyclotron resonance (ICR). These typically require a coaxial magnetic field for wave propagation.